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Cobalt(II) fluoride
・ Cobalt(II) formate
・ Cobalt(II) hydroxide
・ Cobalt(II) iodide
・ Cobalt(II) naphthenate
・ Cobalt(II) nitrate
・ Cobalt(II) oxalate
・ Cobalt(II) oxide
・ Cobalt(II) phosphide
・ Cobalt(II) selenide
・ Cobalt(II) sulfate
・ Cobalt(II) thiocyanate
・ Cobalt(II,III) oxide
・ Cobalt(III) fluoride
・ Cobalt(III) nitrate


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Cobalt(II) fluoride : ウィキペディア英語版
Cobalt(II) fluoride

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Cobalt(II) fluoride is a chemical compound with the formula (CoF2). It is a pink crystalline solid compound which is antiferromagnetic at low temperatures (TN=37.7 K)〔Ashcroft/Mermin: Solid State Physics (Tab. 33.2)〕 The formula is given for both the red tetragonal crystal, (CoF2), and the tetrahydrate red orthogonal crystal, (CoF2·4H2O). CoF2 is used in oxygen-sensitive fields, namely metal production. In low concentrations, it has public health uses.
CoF2 is sparingly soluble in water. The compound can be dissolved in warm mineral acid, and will decompose in boiling water. Yet the hydrate is water-soluble, especially the di-hydrate CoF2·2H2 O and tri-hydrate CoF2·3H2O forms of the compound. The hydrate will also decompose with heat.
==Preparation==
Cobalt(II) fluoride can be prepared from anhydrous cobalt(II) chloride or cobalt(II) oxide in a stream of hydrogen fluoride:
:CoCl2 + 2HF → CoF2 + 2HCl
:CoO + 2HF → CoF2 + H2O
It is produced in the reaction of cobalt (III) fluoride with water.
The tetrahydrate cobalt(II) fluoride is formed by dissolving cobalt(II) in hydrofluoric acid. The anhydrous fluoride can be extracted from this by dehydration. Other synthesis can occur at higher temperatures. It has been shown that at 500 °C fluorine will combine with cobalt producing a mixture of CoF2 and CoF3.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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